I have unpublished results. I mean, I attempted to publish a work entitled Unusual organic chemistry in tetrahedron Letters 2014. This work was rejected by the editor in 2015. This fact completely stopped my other works with similar subject. I will not to try publish works about the words unexpected, unprecedented and even abnormal which we can find in many chemical publication issued in famous chemical journals. Maybe it is too early time to this a little more humanistic approach to chemistry. Okay, it is not my first and not my last defeat. Anyway, I want to show a small piece of my approach to find a chemical context of the word unexpected in Tetrahedron Letters 1995. The table below shows my first attempts to find some order within this problem.
Table of the descriptions of the word of unexpected in Tetrahedron Letters 1995
(1995TL<Tetrahedron Lett.>number)
No.
|
Source
|
First Description
|
Second Description
|
1995TL0899
|
outcome
|
Nb catalysis
|
|
1.
|
1995TL1499
|
formation
|
Rh catalysis
|
2.
|
1995TL1671
|
debenzylation
|
with lithium bases
|
3.
|
1995TL2199
|
behavior
|
asymmetric dihydroxylation
|
4.
|
1995TL2373
|
subsequent alkylations
|
of triflatres
|
5.
|
1995TL2795
|
formation
|
hydride reduction
|
6.
|
1995TL4027
|
participation
|
nitrogen protecting group
|
7.
|
1995TL5539
|
rearrangement
|
ionic - hypoiodite
|
8.
|
1995TL5637
|
synthesis
|
via two step reaction
|
9.
|
1995TL5677
|
arylation
|
palladium catalysis
|
10.
|
1995TL5895
|
formation
|
RuO2 catalysis
|
11.
|
1995TL6503
|
insertion
|
into benzylic position
|
12.
|
1995TL7153
|
reactivity
|
with benzoquinones
|
13.
|
1995TL7539
|
formation
|
nucleophilic displacement
|
14.
|
1995TL7539
|
cycloaddition
|
acyl-nitroso compounds
|
15.
|
1995TL8531
|
rearrangement
|
photochemical
|
16.
|
1995TL8829
|
reduction product
|
propargylic alcohols
|
17.
|
1995TL9293
|
rearrangement
|
transmetalation
|
18.
|
1995TL9471
|
effect
|
OH group in nucl. addition
|
19.
|
1996TL0291
|
dehydration
|
in basic conditions
|
20.
|
1996TL1233
|
alkylation
|
amines, acids and phenols
|
21.
|
1996TL5365
|
result
|
formylation
|
22.
|
1997TL0115
|
Pictet-Spengler reaction
|
side reaction
|
23.
|
1997TL0305
|
decarboxylation
|
oxidative
|
24.
|
1997TL3297
|
intermolecular cyclization
|
ten membered ring
|
25.
|
1997TL3381
|
Wittig reaction
|
to isopropenyl groups
|
26.
|
1997TL6465
|
formation
|
of 1,3-diols
|
27.
|
1998TL8285
|
intramolecular cyclization
|
Diels-Alder
|
28.
|
1998TL9813
|
allomer
|
of chlorophyll
|
29.
|
1999TL9249
|
formation
|
Sonogashira conditions
|
30.
|
2000TL0391
|
ring formation
|
electrocyclization
|
31.
|
2000TL1763
|
cathodic cleavage
|
to phenoxy ions
|
32.
|
2000TL2105
|
cycloadduct
|
isocyanate reaction
|
33.
|
2000TL3471
|
mechanism
|
increase of selectivity
|
34.
|
2000TL7093
|
formylation, acylation
|
by DMSO
|
35.
|
2001TL1351
|
behavior
|
metalation, formylation
|
36.
|
2001TL2305
|
synthesis
|
intramol. ring enlargement
|
37.
|
2001TL3283
|
ring opening
|
at low temp.
|
38.
|
2001TL5117
|
synthesis
|
of coumarins
|
39.
|
2001TL8539
|
activating effect
|
of the amino group
|
40.
|
2001TL8985
|
ring enlargement
|
C ring
|
41.
|
2002TL5311
|
ring opening
|
anionic
|
42.
|
2002TL7739
|
isomerization
|
base promoted
|
43.
|
2002TL8025
|
macrocyclization
|
highly regioselective
|
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